The use of landfills as containment for municipal solid waste management has received wide acceptance the world over. Its development in countries like Nigeria is constrained by high cost and scarcity of synthetic liners in the local markets. Exploration of the abundant locally available clay deposits in the country’s sedimentary Basins will prove economical, provided it satisfies the standard specifications for design and construction of landfill liners. This study thus evaluates the suitability of shales from three formations (Enugu, Ameki and Imo) within Anambra Basin of Southeastern Nigeria as liner materials. Geotechnical tests such as particle size distribution, Atterberg’s limits, compaction, coefficient of permeability and consolidation were performed on the shale samples. Geochemical analyses involving the inductively coupled plasma emission spectroscopy (ICPES) and cation exchange capacity (CEC) were also conducted; all employing standard methods. Based on the Unified Soil Classification System (USCS), Enugu and Imo shales contain high-plastic inorganic clay, while Ameki shales comprise low–medium plastic inorganic clay. Coefficient of permeability result ranging from 9.12×10-6 to 2.14×10-6cm/s indicates an increase above the standard specification. Expectedly, the cation exchange capacity (CEC), compressibility and plasticity index of the shales are positively related suggesting strong influence of the geotechnical properties on their sorption potentials. Overall assessment revealed that the high hydraulic conductivity and swelling potentials of the shales are not suitable for natural clay liners. Nevertheless, Enugu and Imo shales can further be stabilized chemically to the desired hydraulic conductivity of liners considering other suitable geotechnical properties and their CECs.
Groundwater samples from 39 wells in different geological settings in Sagamu area, Southwestern Nigeria were analysed for their hydrochemical properties, to determine their suitability for domestic and irrigation purposes. The samples were subjected to chemical analysis involving the Induced Coupled Plasma Mass Spectrometry (ICPMS) for cation determination, and volumetric analysis to determine the anions. The classification of the groundwater using Piper diagram, Gibbs variation, Wilcox classification and Zhang evolution plot reveals the distribution of groundwater quality in the area. Parameters like Sodium Absorption Ratio (SAR), Magnesium Adsorption Ratio (MAR) Kelly’s Ratio (KR), Permeability Index (PI), Residual Sodium Bicarbonate (RSBC), and chloro-alkaline indices (CAI), were calculated for irrigation purposes. The results were presented as spatial distribution maps for interpretation and further inferences. Comparison of the groundwater quality in the area with local and international standards indicates that 94.9% of the groundwater within the area is generally suitable for domestic and irrigation purposes.
This study provides a model for the prediction of groundwater potential and vulnerability of basement aquifers in parts of Akure, Southwestern Nigeria. Hydrogeophysical surveys involving very-low-frequency electromagnetic (VLF-EM) profiling and electrical resistivity (ER) sounding, as well as evaluation of hydraulic gradient using three-point method, were carried out. Ten VLF-EM reconnaissance survey traverses, with lengths ranging from 55 m to 75 m, at 10 m station separation, and 12 vertical electrical sounding (VES) stations were occupied. Two-dimensional map of the filtered real component reveals areas of high conductivity, indicative of linear features that can serve as a reservoir or conduit for fluid flow. Interpretation of the VES results delineates three to four geoelectric units. Two aquifer zones were identified, with resistivity values in the ranges of 20 Ωm to 310 Ωm and 100 Ωm to 3,000 Ω m, respectively. Transverse resistance, longitudinal conductance, coefficient of anisotropy and hydraulic gradient have values ranging from 318.2 Ωm2 to 1,041.8 Ωm2, 0.11 mhos to 0.39 mhos, 1.04 to 1.74 and 0.017 to 0.05, respectively. The results of this study identified two prospective borehole locations and the optimum position to site the proposed septic system, based on the aquifer’s protective capacity and groundwater flow properties.
Assessment of baseline physico-chemical parameters and bathymetry mapping of Mahin Lake has been carried out for effective and sustainable utilization, management, conservation, and exploitation of its resources. pH, temperature, dissolved oxygen, electrical conductivity, resistivity, total dissolved solid (TDS), salinity, and surface pressure were determined in situ; while concentrations of calcium, magnesium, sodium, potassium, chloride, nitrate, and phosphate in water samples were determined in the laboratory. Bathymetry map revealed that the deepest portion of the lake is 4.3 m, while surface area and estimated volume of water were 1.82×106 m2 and 4.48×106 m3, respectively. The parameters measured shows considerable spatial variations. Mahin Lake is classified as a freshwater lake, indicating little interaction with the Atlantic Ocean; while its water is classified as ‘soft’ and weakly mineralized considering Ca2+ (0.46 to 1.69 mg/L), Mg2+ (0.55 to 1.83 mg/L), pH (5.05 to 5.5) and electrical conductivity (72.75 to 95.75 μS/cm). With these result, growth, biodiversity, and productivity of marine organisms within the lake are at risk. The low dissolved oxygen concentration (DO, 0.04 to 0.91 ppm) tends towards anoxia status and can possibly cause fauna depletion. Trace anthropogenic impact were identified on the western flank of the lake. The status of the lake provides a guide to further research in determination of its tectonic evolution. Sustainable environmental management system is required to prevent possible anthropogenic activities which can further reduce the quality of Mahin Lake and its associated ecosystem.